Hydrogen and halogen bonding drive the orthogonal self-assembly of an organic framework possessing 2D channels.

نویسندگان

  • Javier Martí-Rujas
  • Luca Colombo
  • Jian Lü
  • Archan Dey
  • Giancarlo Terraneo
  • Pierangelo Metrangolo
  • Tullio Pilati
  • Giuseppe Resnati
چکیده

Orthogonal self-assembly of an open organic framework showing 2D channels has been obtained by combining hydrogen and halogen bonding. The framework is able to host various guest molecules with a diverse set of steric demands and substitution patterns, and survives single-crystal-to-single-crystal guest exchanges from liquid and gas phases.

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عنوان ژورنال:
  • Chemical communications

دوره 48 66  شماره 

صفحات  -

تاریخ انتشار 2012